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De thi dai hoc nam 2014 lan 2 mon hoc hoc cua Nhat Ban

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(liter)

0◦ C 1.0 × 105 Pa (=1.0 atm)

(standard state)
(ideal gas)

22.4 L/mol

(molar volume)

R = 8.31 × 103 Pa·L/(K·mol)

(gas constant)
(Avogadro constant)

NA = 6.0 × 1023 /mol

(Faraday constant)

F = 9.65 × 104 C/mol

(atomic weight)

1

L

(periodic table)

1



H 1.0

C 12

Cu 64

Br 80

(first period)

N 14

4

O 16

Mg 24

Cl 35

(element)
4

K

1
Al
K
Fe


(main group element)
(alkaline earth metal)
(transition element)

He
F

(

first ionization energy)

(electronegativity)

1


(covalent crystal)

2

2
BaSO4

CaO

(pyrite) FeS2

3


CO2

O2

SiO2

(reaction formula)

(coefficient) x

3

5

y Fe2O3 + SO2

11

12

7

(density)

4

4 FeS2 + xO2

14


1.25g/L

4
CH4

CO2

H2

2

N2

O2


5

(volume)

100mL

C2H2O4

(volumetric flask)

100mL

g
(a)


0.10mol/L

(marked line)

(b)

5

g
0.90

a

0.90

b

9.0

a

9.0

b

90

a


90

b

3


6

CH3OH

CO

(catalyst)

H2

(thermochemical equation)
CO(

) + 2 H2 (

)

CH3OH(

) + 92 kJ

(equilibrium state)


6

(forward reaction)

(reverse reaction)
mol

(equilibrium)

4

1 1


A

7

B

7

A

CH3COOHaq

0.050mol/L

(degree of electrolytic dissociation) 0.020
B


NaOHaq

0.10mol/L

A

pH

4

B

pH

12

A 20mL

B 10mL

pH

A

100

pH

2


B

100

pH

2

7

(oxidation-reduction reaction)

8

8

2 KMnO4 + 5 H2O2 + 3 H2SO4

H2O2

O

H2O2

2mol
KMnO4
H2SO4

2 MnSO4 + 5 O2 + 8 H2O + K2SO4


(oxidation number)

−1

0

(oxidizing agent)
KMnO4

5mol

H2O2

10mol

Mn
(acidity)

5

(electron)


(platinum electrode)

9
3860

(electrolysis)


(II)

CuSO4aq

(cathode)

0.25A

(electric current)
(mass)

9

g
H2

0.0020

H2

0.010

Cu

0.064

Cu

0.32


O2

0.016

O2

0.080

6


KNO3

10

100g
60◦ C

50g

(solubility)
(solute)

g
10◦ C

50g

(deposit)


g

10 g

4.4

16

39

7

46

78


(halogen)

11

11
(halogen atom)

(oxidation number)

(valence electron)
Cl2


H2

Cl2

(a)

12

Br2

7

(normal temperature)
F2
(oxidizing power)
F2

−1

I2

(normal temperature and pressure)

(e)

Cl2

SO2


12
(a)
(b)

(IV) MnO2
Fe

(c)

conc.HCl

dil.H2SO4
(II) FeS
NaCl

(d)
(e)

conc.H2SO4
NaHSO3

Cl2

SO2

a

b

a


c

a

e

d

b

d

c

d

e

8


(atom)

13

(oxidation number)

13


NH3

H2SO4

(a)

14

FeCl3

0.01mol/L

(d)

K2CrO7

0.01mol/L

KMnO4

CuSO4aq

(II)

(precipitate)

14

( a ) BaCl2
a


15

8.0g

b

( c ) NaCl

(b) H2S
a

c

Mg

a

0.50mol/L

d

b

(d) ZnCl2

c

b


HClaq 500mL

d

c

d

H2

L

15 L
2.8

3.7

5.6

9

7.4

15


(molecular formula) C5H10

16


(chain hydrocarbon)

(isomer)
(cis-trans

isomer)

16

5

6

7

8

(alkene) A

17

(product)

Cl2
A

(mass)

Br2


9

(addition reaction)
A

140g
A

460g

(number of carbon

atoms)

17

4

5

6

7

10

8

9



(structural formula)

18

(organic compound)

18

H
CH3 CH2 C

CH3

OH

Na

CO2
K2Cr2O7aq

(acidified with sulfuric acid)

(oxidation)

(silver mirror test)
(iodoform reaction)
(dehydration)

(alkene)


B

19

1

A

(reduction reaction)

19

A
a

B

(nitrobenzene)

b

(aniline)

(benzene)

c

(chlorobenzene)
(acetylene(ethyne))


d

(acetone)

e

(acetaldehyde)
2-

(2-propanol)

(salicylic acid)

(acetylsalicylic acid)

a

b

a

d

a

e

b


c

b

d

b

e

c

d

d

e

11


(polymer) ( a )

20

(addition polymerization)

(d)

20


(a)

66(6,6-

)(nylon6,6)
(polyacrylonitrile)

(b)
(c)

(poly(ethylene terephthalate))
(poly(vinyl chloride))

(d)
a

b

a

c

a

d

b

12


c

b

d

c

d



×