MATERIAL SAFETY DATA SHEET
According to EC Directive 2001/58/EC
ZIPPER®
Version 1.0

Approved: 15-03-2005
Revised: 15-03-2005

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE
COMPANY/UNDERTAKING
Product name
COMPANY NAME
Address

Telephone
Telefax

ZIPPER®
MODIFY B.V.
Helmkade 4
NL-1901 BM Castricum
The Netherlands
+31 – (0)251 – 657613
+31 – (0)251 – 670894

2. COMPOSITION/INFORMATION ON INGREDIENTS
Components/ Chemical name
Polyether modified polysiloxane

CAS-No

EINECS

13418076-0

Contents
%
≥75

Symbols
Xi/Xn

Oxirane, methyl-,polymer with
oxirane, mono[3-[1,3,3,3,tetramethyl-1[(trimethylsilyl)oxy]disiloxanyl]propyl]
ether

Rphrases
20/2138-4151/53

3. HAZARDS IDENTIFICATION
Harmful by inhalation and in contact with skin.
Irritating to skin.
Risk of serious damage to eyes.
Toxic for aquatic organisms, may cause long-term adverse effects in the aquatic
environment.

4. FIRST AID MEASURES
Eye contact

•


Skin contact

•
•

Inhalation

•
•
•
•

Flush eyes for 15 minutes or more. If irritation
persists, consult a physician (preferably an
eye specialist) and show MSDS.
Remove contaminated clothing.
Immediately and thoroughly, wash off with
soap and water.
Remove individual from site of exposure to
fresh air.
If not breathing, give artificial respiration.
If breathing is difficult, give oxygen.
Get immediate medical attention.

Printing date: 14-6-2007

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MATERIAL SAFETY DATA SHEET

According to EC Directive 2001/58/EC
ZIPPER®
Version 1.0
Ingestion

•

Approved: 15-03-2005
Revised: 15-03-2005
If swallowed, seek medical attention and
show MSDS.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media

Extinguishing media which must
not be used for safety reasons
Products in case of fire

Specific methods/further
information

•
•
•
•
•

Carbon dioxide.
Foam.

Dry powder.
Water spray.
Not applicable.

•

•

In the event of a fire, the following can be
released: carbon monoxide, carbon dioxide,
silicon dioxide
Collect contaminated fire-fighting water
separately.
Prevent water from entering drains.
Do not flush into surface water or sanitary
sewer systems.
Wear self-contained breathing apparatus for
fire-fighting and full protective gear.
None with proper handling and storage.

•

Combustible liquid, Class IIIB.

•
•
•

Special protective equipment for
firefighters

Hazardous decomposition
products
OSHA flammable class

•

6. ACCIDENTAL RELEASE MEASURES
Methods for cleaning up

Small spills:
•
Use personal protective equipment.
•
Take up with absorbent material (dry sand or
earth, universal binder)
•
Do not allow to enter drains, waterways or
sanitary sewer systems.

7. HANDLING AND STORAGE
Handling
Technical measures/Precautions

•
•
•

In accordance with local and national
regulations.
Avoid formation of vapors and aerosols during

processing and application.
Wear respiratory protection when spraying.

Printing date: 14-6-2007

Page 2/6


MATERIAL SAFETY DATA SHEET
According to EC Directive 2001/58/EC
ZIPPER®
Version 1.0

Approved: 15-03-2005
Revised: 15-03-2005

Storage
Technical measures/Precautions

•
•
•

In accordance with local and national
regulations.
Keep container tightly closes.
Keep away from food and drink..

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
OSHA hazardous components (29 CFR 1910.1200)

Components/ Chemical name
Oxirane, methyl-,polymer with
oxirane, mono[3-[1,3,3,3,tetramethyl-1[(trimethylsilyl)oxy]disiloxanyl]propyl]
ether

CAS-No
134180-76-0

Basis
OSHA PEL

Type
TWA

Value
Not
established

Personal protection equipment
General protective measures

•
•

Eye protection

•
•

Hand protection

Skin and body protection
Respiratory protection

•
•
•

Engineering

•

Do not smoke, eat or drink when using this
product.
Wash hands before breaks and at end of
work shift.
Protective ointment is recommended.
Safety goggles and/or face shield are
recommended for use.
PVC gloves.
Light protective clothing is required.
In case of formation of aerosols or vapors, an
organic vapor cartridge respirator is
recommended.
Good (mechanical) ventilation should be
sufficient to control airborne levels.

9. PHYSICAL AND CHEMICAL PROPERTIES
Form
Colour
Odour

Melting temperature
Boiling temperature
Vapour pressure
Density
Water solubility

Liquid
Light yellow
Characteristic
Not measured
Not measured
Not measured
Approximately 1.02 g/cm3
Soluble

Printing date: 14-6-2007

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MATERIAL SAFETY DATA SHEET
According to EC Directive 2001/58/EC
ZIPPER®
Version 1.0
pH
Viscosity, dynamic

Approved: 15-03-2005
Revised: 15-03-2005


8 @ 40 g/l of water @ 25 °C
Approximately 40 – 90 mPa.s @ 25 °C.
Method: DIN 53019
15.15 g/l. Percentage non-volatile: 98.5%
102 °C (DIN EN 22719) (DIN 51758)
Unknown

Volatile organic compound
Flash point
Partition coefficient nOctanol/Water

10. STABILITY AND REACTIVITY
Conditions to avoid
Thermal decomposition
Hazardous reactions
Hazardous polymerisation
Stability
Hazardous decomposition products

None with proper handling and storage
Not measured
No hazardous reactions with proper handling and
storage
No
Product is stable with proper storage
None with proper handling and storage

11. TOXICOLOGICAL INFORMATION
Acute oral toxicity
Acute inhalation toxicity


Acute dermal toxicity
Skin irritation
Eye irritation
Sensitization
Note

LD50 rat: 3200 mg/kg
LC50 aero rat: 1.08 mg/l
Exposure time 4 hours
Method: OECD 403
LD50 rabbit: 1550 mg/kg
LD50 rat: > 2000 mg/kg
Rabbit: slightly irritant
Rabbit: strongly irritant
Guinea pig: non sensitizing
Toxicological data refer to the undiluted 100%
product.

12. ECOLOGICAL INFORMATION
Ecotoxicity effects
Toxicity to fish
Toxicity to Daphnia
Toxicity to algae

Note

LC50 rainbow trout: 2.1 mg/l
EC50 Daphnia magna: 1.1 mg/l
EC50 Scenedesmus subspicatus: 28.2 mg/l

Refers to biomass
EC50 Scenedesmus subspicatus: 152.2 mg/l
Refers to growth rate
Toxicological data refer to the undiluted 100%
product.

Printing date: 14-6-2007

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MATERIAL SAFETY DATA SHEET
According to EC Directive 2001/58/EC
ZIPPER®
Version 1.0

Approved: 15-03-2005
Revised: 15-03-2005

Note: The product is considered to be a water pollutant (German law).

13. DISPOSAL CONSIDERATIONS
Dispose of in accordance with local, state and federal regulations.
Product disposal and disposal
requirements
Contaminated packaging

In accordance with local authority regulations, take to
special waste incineration plant
If empty contaminated containers are recycled or

disposed of, the receiver must be informed about
possible hazards.

14. TRANSPORT INFORMATION
Road transport
UN-No
Class
Packing group
Proper shipping name
Hazard release

3082
9
III
ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
Polyethersiloxane

Sea transport (IMDG)
UN-No
Class
Packing group
MFAG
EmS
Proper shipping name
Hazard release
Label

3082
9

III
F-A S-F
ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
Polyethersiloxane
9

Air transport (ICAO/IATA)
UN-No
Class
Packing group
Proper shipping name
Hazard release
Label

3082
9
III
ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
Polyethersiloxane
9

Printing date: 14-6-2007

Page 5/6


MATERIAL SAFETY DATA SHEET
According to EC Directive 2001/58/EC

ZIPPER®
Version 1.0

Approved: 15-03-2005
Revised: 15-03-2005

15. REGULATORY INFORMATION
United States of America
SARA Section 311/312

SARA Sections

TSCA (Toxic Substance Control
Act

TSCA
California Proposition 65 Statement

Canada

Fire: NO
Pressure generating: NO
Reactivity: NO
Acute: YES
Chronic: NO
SECTION 313
Notification: NO
This product contains no SARA Title III, Section 313
listed chemicals.
TSCA Inventory

Notification: YES
All intentional ingredients are listed in the TSCA
Inventory or comply with TSCA Polymer Exemption
criyeria per 40CFR723
Section 13
Notification: YES
Notification: NO
This product does not contain any substance(s) which
are defined by the State of California to cause cancer,
birth defects, or other reproductive effects.

WHMIS CLASSIFICATION
Class D, Division 2, Subdivision B
Canadian Environmental Protection Act
All intentional ingredients are listed on the DSL
(Domestic Substance List) or have been notified
pursuant to the NSN regulations.

16. OTHER INFORMATION
HMIS Codes

Manufacturer disclaimer

Fire: 1
Health: 2
Physical Hazard: 0
Protection: X
While the information and recommendations
contained herein are believed to be accurate, we
make no warranty with respect hereto and disclaim all

liability from reliance thereon.

END OF SAFETY DATA SHEET
Printing date: 14-6-2007

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